Preliminary Ar-Ar geochronology of Mesozoic alkaline-carbonatitic to tholeiitic magmatism in the Quilengues area, SW Angola

Authors

DOI:

https://doi.org/10.21701/bolgeomin/136.1/009

Keywords:

Ar-Ar geochronology, Alkaline-carbonatitic magmas, Bimodal magmatism, Mesozoic, Angola

Abstract


New geochronological data have been obtained on kimberlitic units related to the Bonga carbonatite massif and basaltic dikes in the Quilengues region of southwestern Angola as part of the National Geological Plan of Angola (PLANAGEO). Ar-Ar dating of mineral separates (phlogopite, amphibole) indicates distinct intrusion pulses for the alkaline-carbonatite magmas of the Bonga Complex (155.2 ± 2.9 Ma) and a NNE-SSW dike assemblage (124.7 ± 2.2 Ma). These ages agree with those reported from coeval volcanic materials in the coastal region, suggesting a direct correlation with lithospheric destabilisation processes induced by the ascent of deep melts, during incipient to progressive stages of the Atlantic rifting and Pangea’s breakup. The basaltic dikes may represent the feeding channels of mantle-derived melts that extruded as Large Igneous Provinces (LIPs), forming the Paraná-Angola-Etendeka Province. The spatio-temporal relationships of the studied bodies are consistent with the intrusion of mantle melts during the early stages of rifting, in directions equivalent to the Lucapa structure and the Atlantic margin. The new age data reinforce the existing dataset of Jurassic-Cretaceous alkaline-carbonatite and bimodal (alkaline to tholeiitic) pulses in Angola and their South American counterparts. A structural control is also suggested, with the later alkaline pulses emplaced along ~E-W directions, related to the progress of rifting and the action of deep transform faults during continental breakup.

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References

Alberti, A., Castorina, F., Censi, P., Comin-Chiaramonti, P., & Gomes, C. B. (1999). Geochemical characteristics of Cretaceous carbonatites from Angola. Journal of African Earth Sciences, 29(4), 735-759. https://doi.org/10.1016/S0899-5362(99)00127-X

Alberti A., Piccirillo, E. M., Bellieni, G., Civetta, L., Comin-Chiaramonti, P., & Morais, E. A. A. (1992). Mesozoic acid volcanics from southern Angola: petrology, Sr-Nd isotope characteristics and correlation with the acid stratoid volcanic suites of the Paranà basin (south-eastern Brazil). European Journal of Mineralogy, 4, 597-604. https://doi.org/10.1127/ejm/4/3/0597

Allsopp, H., & Hargraves, R. (1985). Rb-Sr ages and palaeomagnetic data for some Angolan alkaline intrusives. Transactions of the Geological Society of South Africa, 88, 295-299.

Amaral, G., Bushee, J., Cordani, U. G., Kawashita, K., & Reynolds, J. H. (1967). Potassium-argon ages of alkaline rocks from southern Brazil. Geochimica et Cosmochimica Acta, 31(2), 117-142. https://doi.org/10.1016/S0016-7037(67)80041-3

Bambi, A. C. J. M. (2015). Metalogenia de las carbonatitas en domínios plutónicos, subvolcánicos y volcánicos: Tchivira, Bonga y Catanda, Angola. PhD Thesis, Universitat de Barcelona, 705 p.

Batumike, J. M., Griffin, W. L., O'Reilly, S. Y., Belousova, E. A., & Pawlitschek, M. (2009). Crustal evolution in the Central Congo-Kasai Craton. Luebo, D.R., Congo: Insights from zircon U-Pb ages, Hf-isotope and trace element data. Precambrian Research, 170(1-2), 107-115. https://doi.org/10.1016/j.precamres.2008.12.001

Cahen, L., Snelling, N. J., Delhal, J., & Vail, J. R. (1984). The geochronology and evolution of Africa: London, Oxford University Press, 512 p.

Carvalho, H. (1982). Carta Geológica de Angola, à escala 1:100.000. lnstituto Investigação Científica Tropical (Centro Geologia), Lisbon.

Carvalho, H. (1983). Notice explicative prèliminaire sur la géologie d'Angola. Garcia de Orta, 6 (1/2), 15-30.

Castillo-Oliver, M., Galí, S., Melgarejo, J. C., Griffin, W. L., Belousova, E., Pearson, N. J., Watangua, M., & O'Reilly, S. Y. (2016). Trace-element geochemistry and U-Pb dating of perovskite in kimberlites of the Lunda Norte province (NE Angola): Petrogenetic and tectonic implications. Chemical Geology, 426, 118-134. https://doi.org/10.1016/j.chemgeo.2015.12.014

Coltorti, M., Alberti, A., Beccaluva, L., Dos Santos, A. B., Mazzucchelli, M., Morais, E., Rivalenti, G., & Siena, F. (1993). The Tchivira Bonga alkaline-carbonatite complex (Angola): petrological study and comparison with some Brazilian analogues. European Journal of Mineralogy, 5, 1001-1024. https://doi.org/10.1127/ejm/5/6/1001

Comin-Chiaramonti, P., Barros Gomes, C., Cundari, Al., Castorina, F., & Censi, P. (2007). A review of carbonatitic magmatism in the Paraná-Angola-Namibia (PAN) system. Periodico di Mineralogia, 76(2-3), 25-78.

Comin-Chiaramonti, P., Cundari, A., De Graff, J. M., Gomes, C. B., & Piccirillo, E. M. (1999). Early Cretaceous-Tertiary magmatism in Eastern Paraguay (western Paraná basin): Geological, geophysical and geochemical relationships. Journal of Geodynamics, 28, 375-391. https://doi.org/10.1016/S0264-3707(99)00016-2

Comin-Chiaramonti, P., Gomes, C. B., Censi, P., & Speziale, S. (2005). Carbonatites from southeastern Brazil: a model for the carbon and oxygen isotope variations. In: Comin-Chiaramonti, P., Gomes, C.B. (eds): Mesozoic to Cenozoic alkaline magmatism in the Brazilian platform. Edusp Fapesp, São Paulo, Brazil, pp. 629-650.

Corner, B., & Durrheim, R. J. (2018). An Integrated Geophysical and Geological Interpretation of the Southern African Lithosphere. In: Siegesmund et al. (eds.), Geology of Southwest Gondwana. Regional Geology Reviews, pp. 19-61. https://doi.org/10.1007/978-3-319-68920-3_2

Da Costa, G. V. (2008). Química mineral e geotermobarometria de xenólitos mantélicos do kimberlito Canastra-01. PhD Thesis, Instituto de Geociências, Universidade de Brasília, 137 p.

Ernst, R. E., & Bell, K. (2010). Large igneous provinces (LIPs) and carbonatites. Mineralogy and Petrology, 98, 55-76. https://doi.org/10.1007/s00710-009-0074-1

Escuder-Viruete, J., Correia, J., & Quintana, L. (2021). Mapa geológico e Notícia explicativa da carta geológica de Namibe. Folhas Sul D-33/S e E-32/Z, 1:250 000. UTE PLANAGEO (IGME, LNEG, IIA), IGEO, Luanda (Angola), 199 p.

Escuder-Viruete, J., & Gumiel, J. C. (2021). Notícia explicativa da carta geológica da Andulo. Folha SUL C-33/X (metade Sul). Escala 1:250 000. UTE PLANAGEO (IGME, LNEG, IIA), IGEO, Luanda (Angola), 227 p.

Farr, H., Phillips, D., Maas, R., & de Wit, R. (2018). Petrography, Sr-isotope geochemistry and geochronology of the Nxau Nxau kimberlites, north-west Botswana. Mineralogy and Petrology, 112, 625-638. https://doi.org/10.1007/s00710-018-0593-8

Galán, G. (2021). Notícia explicativa da carta geológica do Quipungo. Folha Sul D-33/O. Escala 1:250 000. UTE PLANAGEO (IGME, LNEG, IIA), IGEO, Luanda (Angola), 194 p.

Issa Filho, A., Dos Santos, A. B. R. M. D., Riffel, B. F., Lapido-Loureiro, F. E. V., & McReath, I. (1991). Aspects of the geology, petrology and chemistry of some Angolan carbonatites. Journal of Geochemical Exploration, 40, 205-226. https://doi.org/10.1016/0375-6742(91)90039-W

Jelsma, H., Barnett, W., Richards, S., & Lister, G. (2009). Tectonic setting of kimberlites. Lithos, 112S, 55-165. https://doi.org/10.1016/j.lithos.2009.06.030

Jelsma H., Phillips, D., Joy, S., Costa, J., Facatino, M., Posser, A., Kumar, M., Wallace, C., Chinn, I., & Henning, A. (2013). Kimberlites from Central Angola: A Case Study of Exploration Findings. In: Pearson et al. (eds), Proceedings of 10th International Kimberlite Conference. Springer, New Delhi, pp. 173-190. https://doi.org/10.1007/978-81-322-1173-0_12

Jelsma, H. A., deWit, M.J., Thiart, C., Dirks, P. H. G. M., Viola, G., Basson, I. J., & Anckar, E. (2004). Preferential distribution along transcontinental corridors of kimberlites and related rocks of Southern Africa. South African Journal of Geology, 107, 301-324. https://doi.org/10.2113/107.1-2.301

Jourdan, F., Féraud, G., Bertrand, H., & Watkeys, M. K. (2007). From flood basalts to the inception of oceanization: Example from the 40Ar/39Ar high-resolution picture of the Karoo large igneous province. Geochemistry, Geophysics, Geosystems, 8(2), 20 p. https://doi.org/10.1029/2006GC001392

Lapido-Loureiro, F. E. V. (1973). Carbonatitos de Angola. Memórias e Trabalhos do Instituto de Investigações Cientificas de Angola, 11.

Lapido-Loureiro, F. E. V. (1968). Sub-volcanic carbonatite structures of Angola. XXIII International Geological Congress, Praga, pp. 147-161.

Lapido-Loureiro, F. E. V. (1995). A mega-província carbonatítica Brasil-Angola e os seus recursos minerais; geologia, petrografia, geoquímica, geologia económica. PhD Thesis, Universidade de Lisboa, 191 p.

Le Roex, A. P., & Lanyon, R. (1998). Isotope and trace element geochemistry of Cretaceous Damaraland lamprophyres and carbonatites, northwestern Namibia: evidence for plume-lithosphere interaction. Journal of Petrology, 39, 1117-1146. https://doi.org/10.1093/petroj/39.6.1117

Linol, B., de Wit, M. J., Barton, E., Guillocheau, F., de Wit, M. C. J., & Colin J. P. (2015). Facies analyses, chronostratigraphy and paleo-environmental reconstructions of Jurassic to Cretaceous Sequences of the Congo Basin. In: de Wit et al. (eds), Geology and Resource Potential of the Congo Basin. Regional Geology Reviews, Springer-Verlag, pp. 135-161. https://doi.org/10.1007/978-3-642-29482-2_8

Ludwig, K. R. (2003). Isoplot 3.00 A Geochronological Toolkit for Microsoft Excel. Berkeley Geochronology Center, Special Publication No. 4.

Machado, F. S. (1959). The volcanic Belt of Angola and its Carbonatites. Leopoldville Meetings, Commission for Technical Co-operation in Africa South of the Sahara, Leopolville, pp. 309-137.

Marsh, J. S., & Swart, R. (2018). The Bero Volcanic Complex: Extension of the Paraná-Etendeka Igneous Province into SW Angola. Journal of Volcanology and Geothermal Research, 355, 21-31. https://doi.org/10.1016/j.jvolgeores.2016.10.011

Marzoli, A., Melluso, L., Morra, V., Renne, P. R., Sgrosso, I., D'Antonio, M., Duarte-Morais, L., Morais, E. A. A., & Ricci, G. (1999). Geochronology and petrology of Cretaceous basaltic magmatism in the Kwanza basin (western Angola) and relationships with the Parana-Etendeka continental basalt province. Journal of Geodynamics, 28, 341-356. https://doi.org/10.1016/S0264-3707(99)00014-9

Melgarejo, J. C., Costanzo, A., Bambi, A. C., Gonçalves, A. O., & Neto, A. B. (2012). Subsolidus processes as a key factor on the distribution of Nb species in plutonic carbonatites: The Tchivira case, Angola. Lithos, 152, 187-201. https://doi.org/10.1016/j.lithos.2012.06.024

Mendes, F. (1968). Mésures Géochronologiques en Angola. PhD Thesis, Clermont-Ferrand, 21 p.

Merino-Martínez, E. (2022). Notícia explicativa da carta geológica da Lola. Folha 316. Escala 1:100 000. UTE PLANAGEO (IGME, LNEG, IIA), IGEO, Luanda (Angola), 184 p.

Merino-Martínez, E., Chinchilla, D., & Chamizo-Borreguero, M. (2021). Notícia explicativa da carta geológica do Ucu Seles (metade Sul). Folha Sul C-33/U. Escala 1:250 000. UTE PLANAGEO (IGME, LNEG, IIA), IGEO, Luanda (Angola), 186 p.

Merino-Martínez, E., & Goicoechea, P. (2021). Notícia explicativa da carta geológica do Lubango. Folha Sul D-33/N. Escala 1:250 000. UTE PLANAGEO (IGME, LNEG, IIA), IGEO, Luanda (Angola), 242 p.

Milner, S. C., le Roex, A. P., & O'Connor, G. M. (1995). Ages of Mesozoic igneous rocks in northwestern Namibia, and their relationship to continental breakup. Journal Geological Society London, 152, 97-104. https://doi.org/10.1144/gsjgs.152.1.0097

Morbidelli, L., Gomes, C. B., Beccaluva, L., Brotzu, P., Conte, A., Ruberti, E., & Traversa, G. (1995). Mineralogical, petrological and geochemical aspects of alkaline and alkaline-carbonatite associations from Brazil. Earth Science Reviews, 39, 135-168. https://doi.org/10.1016/0012-8252(95)00031-3

Moore, A., Blenkinsop, T., & Cotterill, F. W. (2008). Controls on post-Gondwana alkaline volcanism in Southern Africa. Earth and Planetary Science Letters, 268, 151-164. https://doi.org/10.1016/j.epsl.2008.01.007

Oliveira, A. L., Schmitz, M. D., Wall, C. J., Crowley, J. L., Macêdo Filho, A. A., & Hollanda, M. H. B. M. (2023). New U-Pb geochronology for the Central Atlantic Magmatic Province, critical reevaluation of high-precision ages and their impact on the end-Triassic extinction event. Science Reports, 13, 5485. https://doi.org/10.1038/s41598-023-32534-3

PMid:37016151 PMCid:PMC10073112

Peate, D. W., Hawkesworth, C. J., & Mantovani, M. S. M. (1992). Chemical stratigraphy of the Paraná lavas (South America): classification of magma types and their spatial distribution. Bulletin of Volcanology, 55, 119-139. https://doi.org/10.1007/BF00301125

Renne, P. R., Ernesto, M., Pacca, I. G., Coe, R. S., Glen, J. M., Prévot, M., & Perrin, M. (1992). The age of Paraná flood volcanism, rifting of Gondwanaland, and the Jurassic-Cretaceous boundary. Science, 258, 975-979. https://doi.org/10.1126/science.258.5084.975

PMid:17794593

Renne, P. R., Glen, J. M., Milner, S. C., & Duncan, A. R. (1996). Age of Etendeka flood volcanism and associated intrusions in southwestern Africa. Geology, 24, 659-662. https://doi.org/10.1130/0091-7613(1996)024<0659:AOEFVA>2.3.CO;2

Renne, P. R., Swisher, C. C., Deino, A. L., Karner, D. B., Owens, T. L., & DePaolo, D. J. (1998). Intercalibration of standards, absolute ages and uncertainties in 40Ar/39Ar dating. Chemical Geology, 145 (1-2), 117-152. https://doi.org/10.1016/S0009-2541(97)00159-9

Riccomini, C., Velázquez, V. F., & Gomes, C. B. (2005). Tectonic controls of the Mesozoic and Cenozoic alkaline magmatism in central-southeastern brazilian platform. In: Comin-Chiaramonti and Gomes (eds.), Mesozoic to Cenozoic Alkaline Magmatism in the Brazilian Platform. Edusp Fapesp, São Paulo, Brazil, pp. 31-55.

Robles Cruz, S. E. (2013). Kimberlites associated with the Lucapa structure, Angola. PhD Thesis, Universitat de Barcelona, 112 p.

Robles-Cruz, S. E., Escayola, E., Jackson, S., Galí, S., Pervov, V., Watangua, M., Gonçalves, A., & Melgarejo, J. C. (2012). U-Pb SHRIMP geochronology of zircon from the Catoca kimberlite, Angola: Implications for diamond exploration. Chemical Geology, 310-311, 137-147. https://doi.org/10.1016/j.chemgeo.2012.04.001

Schärer, U., Corfu, F., & Demaiffe, D. (1997). U-Pb and Lu-Hf isotopes in baddeleyite and zircon megacrysts from the Mbuji-Mayi kimberlite: constraints on the subcontinental mantle. Chemical Geology, 143, 1-16. https://doi.org/10.1016/S0009-2541(97)00094-6

Silva, A. T. F., Torquato, J. R., & Kawashita, K. (1973). Alguns dados geocronológicos pelo método K/Ar da região de Vila Paiva Couceiro, Quilengues e Chicomba (Angola). Serviço de Geologia e Minas de Angola, 24, 29-46.

Svensen, H. H., Torsvik, T. H., Callegaro, S., Augland, L., Heimdal, T. H., Jerram, D. A., Planke, S., & Pereira, E. (2017). Gondwana Large Igneous Provinces: plate reconstructions, volcanic basins and sill volumes. In: Sensarma and Strorey (eds), Large Igneous Provinces from Gondwana and Adjacent Regions. Geological Society, Special Publications, 463, pp. 17-40. https://doi.org/10.1144/SP463.7

Torquato, J. R. (1977). Geotectonic Outline of Angola. Cahiers de l'Office de la Recherché Scientífique et Technique Outre-Mer (O.R.S.T.O.M.), Série Geólogie, 9 (1/2), 15-34.

Torquato, J. R., & Amaral, G. (1973). Idade K/Ar em rochas de Catanda e Vila de Almoster. Instituto de Investigação Científica de Angola, Boletim, 10 (1), 89-95.

Torsvik, T. H., Rousse, S., Labails, S., & Smethurst, M. A. (2009). A new scheme for the opening of the South Atlantic Ocean and the dissection of an Aptian salt basin. Geophysics Journal International, 177, 1315-1333. https://doi.org/10.1111/j.1365-246X.2009.04137.x

Vale, F. S., Graça da Cruz, A., Simões, M., & Pereira, E. (1972). Carta Geológica de Angola, à escala 1:100.000. Folha 316 (Dinde-Lola). Direcção Provincial dos Serviços de Geologia e Minas, Angola.

Woolley, A. R. (2001). Alkaline Rocks and Carbonatites of the World. Part 3: Africa. The Geological Society of London, 372 p. ISBN: 1-86239-083-5

Published

2025-08-22

How to Cite

Merino-Martínez, E., Valverde-Vaquero, P., Beranoaguirre, A., Galán, G., Gabites, J., & Manuel, J. (2025). Preliminary Ar-Ar geochronology of Mesozoic alkaline-carbonatitic to tholeiitic magmatism in the Quilengues area, SW Angola. Boletín Geológico Y Minero, 136(1), 009. https://doi.org/10.21701/bolgeomin/136.1/009

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