Capa reactiva innovadora para la mejora del tratamiento suelo-acuífero: exitosa instalación en el acuífero del Llobregat (Cataluña, ne españa)

Autores/as

  • M. Hernández CeTaqua, Water Technology Center
  • O. Gibert CeTaqua, Water Technology Center
  • X. Bernat CeTaqua, Water Technology Center
  • C. Valhondo IDAEA-CSIC Institute of environmental Assessment and Water Research
  • M. Köck-Schulmeyer IDAEA-CSIC Institute of environmental Assessment and Water Research
  • M. Huerta-Fontela AMB Laboratory
  • M. V. Colomer ACA Water Catalan Agency

DOI:

https://doi.org/10.21701/bolgeomin.125.2.003

Palabras clave:

Balsa de Infiltración, Capa Reactiva, Contaminantes Emergentes, Recarga de Acuíferos, Río Llobregat, Tratamiento Suelo-Acuífero

Resumen


El proyecto Life+ ENSAT ha demostrado la eficiencia en la mejora de la calidad del agua de recarga mediante la instalación de una capa reactiva en un sistema de recarga de acuíferos. La capa, constituida principalmente por compost vegetal, fue instalada en la sub-superficie de una balsa de recarga construida en el Valle Bajo del Llobregat (provincia de Barcelona), con el objetivo de promover la biodegradación y mejorar la eliminación de microcontaminantes emergentes del agua del Llobregat. El exhaustivo seguimiento de la calidad del agua que incluye química general, contaminantes emergentes y sustancias prioritarias, indica que los cambios hidrobiogeoquímicos con el sistema implantado mejoran los procesos de desnitrificación y la reducción de concentración de gemfibrozilo y carbamazepinaepoxy). Esta mejora se debe a la liberación de carbón orgánico disuelto, que promueve los procesos de biodegradación a escala local en la zona no saturada, sin efecto en los piezómetros de control más alejados. La capa reactiva sigue activa después de más de tres años desde su instalación.

La evaluación económica de la capa reactiva muestra que es una solución prometedora para la mejora de la recarga de acuíferos con aguas de baja calidad, no sólo desde el punto de vista técnico, sino desde el punto de vista de la sostenibilidad económica.

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Citas

AMB, 2011. Dades Ambientals 2011. 20/03/2013. http://www.dadesambientals.cat/

Amy, G; Drewes, J, (2007). Soil aquifer treatment (SAT) as a natural and sustainable wastewater Reclamation/ Reuse technology: Fate of wastewater effluent organic matter (efOM) and trace organic compounds. Environmental monitoring and assessment 129 (1-3) 19-26. https://doi.org/10.1007/s10661-006-9421-4

Barbieri, M., Carrera, J., Sánchez-Vila, X., Ayora, C., Cama, J., Koeck-Schulmeyer, M., López de Alda, M., Barceló, D., Tobella Brunet, J., Hernández García, M., 2011. Microcosm experiments to control anaerobic redox conditions when studying the fate of organic micropollutants in aquifer material. Journal of Contaminant Hydrology 126, 330-345. https://doi.org/10.1016/j.jconhyd.2011.09.003

Boleda, R. M., Galcedran, T., Ventura, F. 2011. Behavior of pharmaceuticals and drugs of abuse in a drinking water treatment plant (DWTP) using combined conventional and ultrafiltration and reverse osmosis (UF/RO) treatments. Environmental Pollution 159 (2011) 1584 - 1591. https://doi.org/10.1016/j.envpol.2011.02.051

Bosma, T. N. P., Ballemans, e. M. W., Hoekstra, N. K., te Welscher, R. A. G., Smeenk, J. G. M. M., Schraa, G., Zehnder, A. J. B. (1996). Biotransformation of Organics in Soil Columns and an Infiltration Area, Ground Water, 34(1), 49-56. https://doi.org/10.1111/j.1745-6584.1996.tb01864.x

Dillon, P., Paveric, P., Page, D., Beringen, H., Ward, J. 2009. Managed Aquifer Recharge, an introduction. Waterlines Report Series, No. 13, February 2009. Australian Government, National Water Commission.

Feitosa-Felizzola, J., Hanna, K., Chiron, S. 2009. Adsorption and transformation of selected human-used macrolide antibacterial agents with iron (III) and manganese (IV) oxides. Environmental Pollution 157 (2009) 1317-1322. https://doi.org/10.1016/j.envpol.2008.11.048

García-Galan, M.J., Garrido, T., Fraile, J., Ginebreda, A., Díaz-Cruz, M.S. and Barceló, D., 2011. Application of fully automated online solid phase extraction-liquid chromatography-electrospray-tandem mass spectrometry for the determination of sulfonamides and their acetylated metabolites in groundwater. Analytical and Bioanalytical Chemistry 399 (2), 795-806. https://doi.org/10.1007/s00216-010-4367-3

Gibert, O., de Pablo, J., Cortina, J. L., Ayora, C. 2004. Chemical characterisation of natural organic substrates for biological mitigation of acid mine drainage. Water Research 38 (2004) 4186-4196. https://doi.org/10.1016/j.watres.2004.06.023

Greskowiak, J. 2005. Reactive transport processes in artificially recharged aquifers. Field and modelling studies. PhD Thesis.

Greskowiak, J., Grpommer, H., Massmann, G., Nützmann, G., (2006) Modeling Seasonal Redox Dynamics and the Corresponding Fate of the Pharmaceutical Residue Phenazone During Artificial Recharge of Groundwater. Environ. Sci. Technol. 2006, 40, 6615-6621. https://doi.org/10.1021/es052506t

Hernández, M., Tobella, J., Ortuño, F., Armenter, J. Ll. 2010. Aquifer recharge for securing water resources: the experience in Llobregat River. Water Science & Technology 63.2 2011. IWA publishing. https://doi.org/10.2166/wst.2011.036

Huerta-Fontela, M., Galceran, M.T., Ventura, F., 2008. Stimulatory drugs of abuse in surface waters and their removal in a conventional drinking water treatment plant. Environmental Science & Technology 42, 6809-6816. https://doi.org/10.1021/es800768h

INe, 2012. Instituto Nacional de estadística. 20/03/2013, http://www.ine.es/

Jesus García-Galán, M., González Blanco, S., López Roldán, R., Díaz-Cruz, S., Barceló, D., 2012. ecotoxicity evaluation and removal of sulfonamides and their acetylated metabolites during conventional wastewater treatment. Science of the Total Environment 437, 403-412. https://doi.org/10.1016/j.scitotenv.2012.08.038

Kampioti, A.A., da Cunha, A.C.B., de Alda, M.L., Barceló, D., 2005. Fully automated multianalyte determination of different classes of pesticides, at picogram per litre levels in water, by on-line solid-phase extraction-liquid chromatography-electrospray-tandem mass spectrometry. Analytical and Bioanalytical Chemistry 382, 1815-1825. https://doi.org/10.1007/s00216-005-3332-z

Köck-Schulmeyer, M., Ginebreda, A., Alda, M.L.d., Barceló, D., 2012b. Fate and Risks of Polar Pesticides in Groundwater Samples of Catalonia. In: Barceló, D. (ed.). Hdb env Chem, pp. 375-394. https://doi.org/10.1007/698_2011_132

Köck-Schulmeyer, M., Ginebreda, A., González, S., Luis Cortina, J., López de Alda, M. and Barceló, D., 2012. Analysis of the occurrence and risk assessment of polar pesticides in the Llobregat River Basin (Ne Spain). Chemosphere 86 (1), 8-16. https://doi.org/10.1016/j.chemosphere.2011.08.034

Köck-Schulmeyer, M., Ginebreda, A., Postigo, C., López-Serna, R., Pérez, S., Brix, R., Llorca, M., Alda, M.L.d., Petrovic, M., Munné, A., Tirapu, L. and Barceló, D., 2011. Wastewater reuse in Mediterranean semi-arid areas: The impact of discharges of tertiary treated sewage on the load of polar micro pollutants in the Llobregat river (Ne Spain). Chemosphere 82 (5), 670-678. https://doi.org/10.1016/j.chemosphere.2010.11.005

Kuster, M., López de Alda, M.J., Hernando M.D., Petrovic, M., Martín-Alonso,J., Barceló, D. (2008). Analysis and occurrence of pharmaceuticals, estrogens, progestogens and polar pesticides in sewage treatment plant effluents, river water and drinking water in the Llobregat river basin (Barcelona, Spain). Journal of Hydrology 358, 112-123. https://doi.org/10.1016/j.jhydrol.2008.05.030

López de Alda, M.J., Gil, A., Paz, e., Barcelço, D., 2002. Occurrence and analysis of estrogens and progestogens in river sediments by liquid chromatography-electrospray-mass spectrometry. The Analyst 127, 1299-1304. https://doi.org/10.1039/B207658F

López de Alda, M.J., Díaz-Cruz, S., Petrovic, M., Barceló, D., 2003. Liquid chromatography-(tandem) mass spectrometry of selected emerging pollutants (steroid sex hormones, drugs and alkylphenolic surfactants) in the aquatic environment. Journal of chromatography. A 1000, 503-526. https://doi.org/10.1016/S0021-9673(03)00509-0

López-Roldán, R., López de Alda, M., Gros, M., Petrovic, M., Martin-Alonso, J. and Barceló, D., 2010. Advanced monitoring of pharmaceuticals and estrogens in the Llobregat River basin (Spain) by liquid chromatography-triple quadrupole-tandem mass spectrometry in combination with ultra performance liquid chromatography-time of flight-mass spectrometry. Chemosphere 80 (11), 1337-1344. https://doi.org/10.1016/j.chemosphere.2010.06.042

López-Serna, R., Jurado, A., Vázquez-Suñé, e., Carrera, J., Petrovic, M. and Barceló, D., 2013. Occurrence of 95 pharmaceuticals and transformation products in urban groundwaters underlying the metropolis of Barcelona, Spain. Environmental Pollution 174, 305-315. https://doi.org/10.1016/j.envpol.2012.11.022

López-Serna, R., Postigo, C., Blanco, J., Perez, S., Ginebreda, A., López de Alda, M., Petrovic, M., Munné, A. and Barceló, D., 2012. Assessing the effects of tertiary treated wastewater reuse on the presence emerging contaminants in a Mediterranean river (Llobregat, Ne Spain). Environmental Science and Pollution Research 19 (4), 1000-1012. https://doi.org/10.1007/s11356-011-0596-z

Maoz, A., Chefetz, B. 2010. Sorption of the pharmaceuticals carbamazepine and naproxen to dissolved organic matter: Role of structural fractions. Water Research 44 (2010) 981-989. https://doi.org/10.1016/j.watres.2009.10.019

Muñoz, I., López-Doval, J.C., Ricart, M., Villagrasa, M., Brix, R., Geiszinger, A., Ginebreda, A., Guasch, H., Jose López de Alda, M., Romani, A.M., Sabater, S. and Barceló, D., 2009. Bridging levels of pharmaceuticals in river water with biological community structure in the Llobregat river basin (northeast Spain). Environmental Toxicology and Chemistry 28 (12), 2706-2714. https://doi.org/10.1897/08-486.1

Otero, N., Soler, A., Canals, A. 2008. Controls of d34S and d18O in dissolved sulphate: Learning from a detailed survey in the Llobregat River (Spain). Applied Geochemistry 23 (2008) 1166-1185. https://doi.org/10.1016/j.apgeochem.2007.11.009

Osorio, V., Marce, R., Perez, S., Ginebreda, A., Cortina, J.L. and Barceló, D., 2012. Occurrence and modeling of pharmaceuticals on a sewage-impacted Mediterranean river and their dynamics under different hydrological conditions. The Science of the total environment 440, 3-13. https://doi.org/10.1016/j.scitotenv.2012.08.040

Pedretti, D., Barahona-Palomo, M., Bolster, D., Sánchez-Vila, X., Fernández-García, D. 2012. A quick and inexpensive method to quantify spatially variable infiltration capacity for artificial recharge ponds using photographic images. Journal of Hydrology 430-431 (2012) 118-126. https://doi.org/10.1016/j.jhydrol.2012.02.008

Petrovic, M., Diaz, A., Ventura, F., Barceló, D., 2003. Occurrence and removal of estrogenic short-chain ethoxy non-ylphenolic compounds and their halogenated derivatives during drinking water production. Environmental Science & Technology 37, 4442-4448. https://doi.org/10.1021/es034139w

Ricart, M., Guasch, H., Barceló, D., Brix, R., Conceicao, M.H., Geiszinger, A., de Alda, M.J.L., Lopez-Doval, J.C., Munoz, I., Postigo, C., Romani, A.M., Villagrasa, M. and Sabater, S., 2010. Primary and complex stressors in polluted mediterranean rivers: Pesticide effects on biological communities. Journal of Hydrology 383 (1-2), 52-61. https://doi.org/10.1016/j.jhydrol.2009.08.014

Rodríguez-Mozaz, S., López de Alda, M.J., Barceló, D. (2004). Monitoring of estrogens, pesticides and bisphenol A in natural waters and drinking water treatment plants by solid-phase extraction-liquid chromatography-mass spectrometry. Journal of Chromatography A, 1045 85-92. https://doi.org/10.1016/j.chroma.2004.06.040

Solé, M., de Alda, M.J.L., Castillo, M., Porte, C., Ladegaard-Pedersen, K., Barceló, D., 2000. estrogenicity determination in sewage treatment plants and surface waters from the Catalonian area (Ne Spain). Environmental Science & Technology 34, 5076-5083. https://doi.org/10.1021/es991335n

Teijon, G. Candela, L., Tamoh, K., Molina-Díaz, A., Fernández-Alba. A.R. 2010. Occurrence of emerging contaminants, priority substances (2008/105/Ce) and heavy metals in treated wastewater and groundwater at Depurbaix facility (Barcelona, Spain). Science of the Total environment 408 (2010) 3584-3595. https://doi.org/10.1016/j.scitotenv.2010.04.041

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Publicado

2014-06-30

Cómo citar

Hernández, M., Gibert, O., Bernat, X., Valhondo, C., Köck-Schulmeyer, M., Huerta-Fontela, M., & Colomer, M. V. (2014). Capa reactiva innovadora para la mejora del tratamiento suelo-acuífero: exitosa instalación en el acuífero del Llobregat (Cataluña, ne españa). Boletín Geológico Y Minero, 125(2), 157–172. https://doi.org/10.21701/bolgeomin.125.2.003

Número

Sección

Artículos

Datos de los fondos

LIFE programme
Números de la subvención LIFE08ENV/E/00117-ENSAT

Ministerio de Ciencia y Tecnología
Números de la subvención CSD2009-00065

Generalitat de Catalunya
Números de la subvención 2009-SGR-965