Quality characterization and evaluation of bentonites from the provinces of San Juan and Río Negro (Argentina) for their use in the oil and ceramics industries
DOI:
https://doi.org/10.21701/bolgeomin.127.4.003Keywords:
Argentina, bentonite, characterization, depositsAbstract
The aim of this research work is to characterize bentonites, both physically and chemically, as well as mineralogically, from deposits located in the Argentine provinces of San Juan and Rio Negro. The study is completed with technological assays to evaluate the quality of the samples under study so as to determine possible industrial uses and/or applications for this material.
To carry out this work, four samples of bentonite, identified as M1, M3, and M4, from the province of San Juan, and another, identified as M2, from the province of Rio Negro were used. Physical characterization consisted of determining: swelling, density, moisture, pH and specific gravity of the bentonite samples through application of a number of techniques. Chemical characterization of major components was carried out by using wet methods through acid attack, whilst ICP was used to characterize minor components. 79 Mineralogical characterization was carried out by using an infrared spectrometer. The technological assays for evaluating the quality of the bentonite were carried out following the method indicated by the API and SEGEMAR standards, among others, in order to determine possible uses and/or applications, mainly in the oil and ceramics industries.
It was found that the M2 bentonite is the most suitable to be used as a drilling mud as it meets the requirements specified by the API standards. The M3 bentonite, due to its physico-chemical characteristics such as low rheology, swelling, low iron content, amongst others, is the most suitable for the ceramics industry.
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References
Arredondo, D. 2009. Resumen de lodos. Informe Inédito, Universidad Autónoma Gabriel Rene Moreno AGRM, Ingeniería Petrolera, Bolivia, 41 págs.
Behrens, A., Giljum, S., Kovanda, J. and Niza, S. 2007. World wide patterns of natural resource extraction and their implications for sustainable use policies. Ecological Economics. Elsevier, 64(2), 444-453. https://doi.org/10.1016/j.ecolecon.2007.02.034
Bernal, I., Cabezas, H., Espitia, C., Mojica, J. and Quintero, J. 2003. Análisis próximo de arcillas para cerámica. Revista de la Academia Colombiana de Ciencias Exactas Físicas y Naturales, 27(105), 569-578. https://doi.org/10.18257/raccefyn.27(105).2003.2092
British Geological Survey, Brown, T. et al. 2009-2013. World Mineral Production. 22/04/2015, http://www.bgs.ac.uk/mineralsUK/statistics/worldStatistics.html.
Camacho, J. y Celada, C. 2004. Definición de zonas potenciales para esmectitas en los Departamentos del Valle del Cauca, Tolima y Caldas. Informe Inédito. Ingeominas, Colombia, 25 págs.
Cerámica y Cristal 140, Editorial Ciclo, 23/04/2015, http://www.ceramicaycristal.com.ar.
Dias, M., Barrios, M. y Prates, S. 2004. Las bentonitas de Benavila (Portugal), caracterización mineralógica y propiedades. Geogaceta, 35, 99-102.
Doval, M., Garcia, E., Luque, J., Martin, J. y Rodas, M. 1991. In: Lunar, R., Oyarzun, R. (ed.), Yacimientos Minerales. Centro de estudios Ramón Arces, Universidad Nacional de Colombia, Colombia, 582-608.
Fundación Okita, 2007. Estudio sobre Cadenas Productivas Seleccionadas en la República Argentina. industria de los minerales no-metalíferos. Informe Inédito. Agencia de Cooperación Internacional del Japón (JICA), Secretaría de Industria Comercio y Minería, Argentina, 118 págs.
Gonzáles, I. 1990. In: García, J. and Martinez, J. (ed.), Yacimientos Minerales. Recursos Minerales de España, Madrid, 96-112.
Guerstein, P. 1982. Estudio geológico del Triásico aflorante entre las Quebradas de Hilario y Carrizal. Departamento de Calingasta. San Juan. Trabajo Inédito. Universidad Nacional de San Juan, Argentina, 47 págs.
Grim, R. E. 1962. Applied Clay Mineralogy. McGraw Hill, New York, 422 pp.
Grim, R.E. and Guven, N. 1978. Bentonites - Geology, Mineralogy, Properties and Uses, Developments in Sedimentology. Elsevier, New York, 596 pp.
Hevia, R. 2007. Bentonitas. Propiedades y usos industriales. Informe Inédito. Proyecto INTI-SEGEMAR, Unión Europea, 13 págs.
Iñiguez, et al. 1972. Estudio geológico - económico de los yacimientos de bentonitas del Lago Pellegrini. Trabajo Inédito. Dirección Minería Provincia Rio Negro, Argentina, 25 págs.
Kelessidis, V., Christidis, G. and Makri, P. 2007. Gelation of water-bentonite suspensions at high temperatures and rheological control with lignite addition. Applied Clay Science, 36(2), 221-231. https://doi.org/10.1016/j.clay.2006.09.010
Laird, D. 2006. Influence of layer charge on swelling of smectites. Applied Clay Science. Elsevier, 34, 74-87. https://doi.org/10.1016/j.clay.2006.01.009
Lazo, S. y Artica, M. 2006. Activación de la bentonita cálcica por vía ácida y su uso en la decoloración y blanqueo de aceites vegetales comestibles. Trabajo Inédito. Facultad de Ingeniería Metalúrgica y de Materiales, Universidad Nacional del Perú, Huancayo, Perú, 112 págs.
Madejová, J. and Komadel, P. 2001. Baseline studies of the clay minerals society source clays: infrared methods. Clays and Clays Minerals, 49(5), 410-432. https://doi.org/10.1346/CCMN.2001.0490508
Marconi, C. 1998. Bentonitas en Argentina. I Jornada en Minerales Industriales. Intemin. Instituto de Geología y Recursos Minerales SEGEMAR. Fundación Empremin, Argentina, 2, 123-157.
Molina, M., Moreno, S. y Fernández, J. 2007. Caracterización de las Arcillas Esmectíticas de la Formación Honda al Noreste del Tolima y su Potencial Aplicación como Catalizadores. XI Congreso de Geología, Colombia, 2, 112-121.
Morgan, et al. 1993. Industrial Minerals Laboratory Manual - Bentonite. British Geological Survey, Mineralogy and Petrography Group, United Kingdom, 10-42 pp.
Newman, A. y Brown, G. 1987. The Chemistry of constitution of clays. In: Newman, A. (ed.), Chemistry of clays and clays minerals, London, 1-128.
Odom, I. 1984. Smectite Clay Minerals: Properties and Uses. Phil Trans. R. Soc. London, 391-409 pp. https://doi.org/10.1098/rsta.1984.0036
Odom, I. 1987. Na-Ca Montmorillonite: properties and uses. Society of Mining Engineers of AIME, Pennsylvania, 282, 1903-1904.
Patterson, S. and Murray, H. 1983. Clays. Industrial Minerals and Rocks, New York, USA, 519-577.
Peña, J. 2007. Estudio para la Optimización del Uso de Fluidos de Perforación en el Campo de Petroproducción. Trabajo Inédito. Facultad de Ciencias de la Ingeniería Escuela de Tecnología en Petróleo Equinoccial, Quito, 156 págs. +10 págs. (anexos).
Ross, C. S. and Shannon, E. U. 1926. The minerals of bentonite and related clays and their physical properties. American Ceramic Society Journal, 77-96. https://doi.org/10.1111/j.1151-2916.1926.tb18305.x
Roskill, 1997. The economics of bentonite. Information 8th Edition, London, 125 pp.
Schalamuk, I.B y Cábaña, M. 1999. Bentonitas de la región precordillera de San Juan y Mendoza. Recursos Minerales de la República Argentina (Ed. E.O. Zappettini). Instituto de Geología y Recursos Minerales SEGEMAR, 35, 921-927.
Teague, K.H. 1972. Southern Bentonite. SME (Society of Mining Engineers). AIME. American Institute of Mining Metallurgical and Petroleum Engineers, Pennsylvania, 72H, 328.
UNSAM. 2007. Información económica de bentonita. Informe Inédito, Publicación técnica, Argentina. 87 págs.
U.S. Geological Survey, 2015. Mineral commodity summaries: U.S. Geological Survey. 22/04/2015, http://minerals.usgs.gov/minerals/pubs/mcs/2015/mcs2015.pdf.
Valles, M. y Impiccini, A. 1999. Bentonitas de la Cuenca Neuquina, Río Negro, Neuquén y la Pampa. Recursos Minerales de la República Argentina (Ed. E.O. Zapettini, Instituto de Geología y Recursos Minerales SEGEMAR), 35, 1113-1125.
Vega, F., Verdeja, L., Sancho, J. y García, J. 1993. Caracterización y propiedades de las bentonitas de Amapote. Boletín Sociedad Española Cerámica y Vidrio, 32(6), 377-383.
Viruel, M.E. y Lombardero, M. 1998. Los minerales industriales y las rocas de aplicación en la Quebrada de Humauaca. Estudio Geológico Integrado de la Quebrada de Humahuaca. Anales XXX. SEGEMAR, 5(3), 32-35.
Wetten, F. y Baraldo, J. 1984. Geología de los yacimientos de bentonitas existentes entre las localidades de Colón y Quebrada Carrizalito, Dto de Calingasta, San Juan. Instituto de Investigaciones Geológicas, Universidad Nacional de San Juan, 5(3), 12-14.
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