Mineralogical and chemical study of Spanish common clays with regard to their use in pelotherapy
DOI:
https://doi.org/10.21701/bolgeomin.122.3.007Keywords:
common clays, mineralogy, pelotherapy, toxic trace elementsAbstract
The mineralogical (whole sample and clay fraction) and chemical compositions of 5 representative samples of Spanish common clays have been studied to evaluate their use in pelotherapy. The mineralogy of the samples revealed clays with phyllosilicate contents of between 53% and 74% and minor quantities of quartz, calcite, dolomite, feldspars, gypsum, pyrite and hematite. Smectite was the predominant clay mineral, with the exception of one sample containing only illite. The results of analyses of the major chemical elements were consistent with the mineralogical composition. The samples contained low quantities (<130 ppm, with the exception of Ba) of potentially harmful elements; the CAR sample contained the highest quantities of Ba, V, Cr, Co, As, Sb, and Ni. Nevertheless, the concentrations of trace elements in the samples analysed showed lower levels of phytotoxicity than those permitted and were also lower than those found in peloids currently used in Spanish spas.
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References
Barahona, E. 1974. Arcillas de ladrillería de la provincia de Granada: evaluación de algunos ensayos de materias primas. Tesis Doctoral. Universidad de Granada. 398 págs.
Bellometti, S., Cecchettin, M., Galzigna, L. 1997. Mud-pack therapy on osteoarthrosis. Changes in serum leves of chondrocyte markers. Clin. Chim. Acta, 268, 101-106. https://doi.org/10.1016/S0009-8981(97)00171-X
Cara, S., Carcangiu, G., Padalino, G., Palomba, M., Tamanini, M. 2000. The bentonites in pelotherapy, chemical, mineralogical and technological properties of materials from Sardinia deposits (Italy). Applied Clay Science, 16, 117-124. https://doi.org/10.1016/S0169-1317(99)00049-6
Carretero, M.I., Gomes, C., Tateo, F. 2006. Clays and human health. In: Bergaya, F.,Theng, B.K.G., Lagaly, G. (Eds.), Handbook of Clay Science. Elsevier, Amsterdam, pp. 717-741. https://doi.org/10.1016/S1572-4352(05)01024-X
Carretero, M.I. y Pozo, M. 2007. Mineralogía Aplicada. Salud y Medio Ambiente. Thomson, Madrid. 406 páginas.
Carretero, M.I., Pozo, M., Pozo, E., Parrales, I.G., Armijo, F., Maraver, F. 2010a. Caracterización física y físico-química de peloides españoles. Estudio de su variabilidad. Macla, 13, 61-62.
Carretero, M.I., Pozo, M., Martín-Rubí, J.A., Pozo, E., Maraver, F. 2010b. Mobility of elements in interaction between artificial sweat and peloids used in spanish spas. Applied Clay Science, 48, 506-515. https://doi.org/10.1016/j.clay.2010.02.016
Carretero, M.I., Pozo M., Sánchez, C., García, F.J., Medina, J.A., Bernabé, J.M. 2007. Comparison of saponite and montmorillonite behaviour during static and stirring maturation with seawater for peloteraphy. Applied Clay Science, 36, 161-173. https://doi.org/10.1016/j.clay.2006.05.010
Cozzi, F., Podswiadek, M., Cardinale, G., Oliviero, F., Dani, F., Sfriso, P., Punzi, L. 2007. Mud-bath treatment in spondylitis associated with antiinflamatory bowel disease - a pilot randomised trial. Jt. Bone Spine 74, pp 436-439. https://doi.org/10.1016/j.jbspin.2006.12.003
Esquevin, J. 1969. Influence de la composition chimique des illites sur leur cristallinité. Bull. Centre. Rech. Pau. S.N.P.A., 3: 147-154.
Galán, E. 2003. Contaminación de suelos por metales pesados y regeneración. En: Emilio Galán Huertos (editor). Mineralogía Aplicada. Síntesis, 267-286.
Galzigna, L., Ceschi-Berrini, C., Moschin, E., Tolomio, C. 1998. Thermal mud-pack as an anti-inflammatory treatment. Biomed & Pharmacother, 52, pp 408-409. Elsevier. https://doi.org/10.1016/S0753-3322(99)80010-9
Galzigna, L., Moretto, C., Lalli, A. 1996. Physical and biochemical changes of thermal mud after maturation. Biomed & Pharmacother, 50, pp 306-308. Elsevier. https://doi.org/10.1016/0753-3322(96)84831-1
Gámiz, E., Martín-García, J.M., Fernández-González, M.V., Delgado, G., Delgado, R. 2009. Influence of water type and maturation time on the properties of kaolinitesaponite peloids. Applied Clay Science 46, pp 117-123. https://doi.org/10.1016/j.clay.2009.07.016
Kabata-Pendias, A. and H. Pendias. 1992. Trace Elements in Soils and Plants, 2nd ed. CRC Press, Boca Raton. 365 p.
Legido, J.L., Medina, C., Mourelle, M.L., Carretero, M.I., Pozo, M. 2007. Comparative study of the cooling rates of bentonite, sepiolite and common clays for their use in pelotherapy. Applied Clay Science, 36, 148-160. https://doi.org/10.1016/j.clay.2006.06.014
Martín Pozas, J.M. 1978. Análisis cuantitativo de fases cristalinas por D.R. III Seminario sobre: Difracción por muestras policristalinas. Método de Debye-Scherrer. Instituto de Ciencias de la Educación. Universidad de Valladolid. 10/13 de Abril de 1978. Ed. José A. de Saja.
Pozo, M. 2008. Propiedades físicas y físico-químicas de las arcillas de interés en centros termales. En: J.L. Legido y M.L. Mourelle (eds.), Investigaciones en el ámbito iberoamericano sobre peloides termales. Universidade de Vigo, Servizo de Publicacións. Congresos 58. 308 pp. ISBN. 978-84-8158-385-4. pp. 61-94.
Pozo, M., Carretero, M.I. 2008. Recursos minerales y salud. Revista Enseñanza de las Ciencias de la Tierra. Monográfico recursos geológicos. Vol. 16 (3), 262-275.
Pozo, M., Carretero, M.I., Maraver, F., Pozo, E., Medina, J.A. 2009. Study of potential availability of trace elements from compositionally different therapeutic muds used in spas. Book of Abstracts. International Symposium on Mineralogy, Environment and Health. Champs-sur-Marne, pp.32-33.
Pozo, M., Pozo, E., Martín Rubí, J.A. 2010a. Caracterización de arcillas españolas para su empleo en la elaboración de peloides termales. En: Libro de Actas del Iº Congreso Nacional de Minerales Industriales. 169-174. (Fueyo editores).
Pozo, M., Carretero, M.I., Pozo, E., Martín Rubí, J.A., Maraver, F. 2010b. Caracterización mineralógica y química de peloides españoles y argentinos. Evaluación de elementos traza potencialmente tóxicos. Libro de resúmenes del II Congreso Iberoamericano de Peloides, págs. 37-38.
Repetto, R., Repetto, G. 2000. Metales. En: E. Mencías Rodríguez y L.M. Mayero Franco (editores). Manual de Toxicología Básica. 619-647.
Schultz, L.G. 1964. Quantitative Interpretation of Mineralogical Composition from X-ray and Chenical Data for the Pierre Shale. Geological Survey Proffesional Paper 391-C. 31 p. https://doi.org/10.3133/pp391C
Setti, M., López-Galindo, A., Fenoll-Hach Alí, P., Viseras, C., Veniale, F. 2004. Healing Clays: need of certification for suitable uses. 8th Congress of Applied Mineralogy, Aguas de Lindoia (Sao Paulo, Brazil), p.54. Abstract.
Smith, K. S., Huyck, H.L.O. 1999. An overview of the abundance, relative mobility, bioavailavility, and human toxicity of metals. En: Plumlee, G.S., y Logsdon, M.J. (editores). The Environmental Geochemistry of Mineral Deposits, Part A: Society of Economic Geologists, Reviews in Economic Geology, v.6A, 29-70. https://doi.org/10.5382/Rev.06.02
Soria, M.L., Repetto, G., Repetto, M. 1995. Revisión general de la toxicología de los metales. En: M. Repetto (editor). Toxicología Avanzada. Díaz de los Santos, Madrid.
Summa, V., Tateo, F. 1998. The use of pelitic raw materials in thermal centres: mineralogy, geochemistry, grain size and leaching test: examples from the Lucania area (southern Italy). Applied Clay Science, 12, 403-417. https://doi.org/10.1016/S0169-1317(97)00024-0
Veniale, F., Barberis, E., Carcagiu G., Morandi, N., Setti, M., Tamanini, M., Tessier, D. 2004. Formulation of muds for pelotherapy: effects of "maduration" by different mineral waters. Applied Clay Science, 25, 135-148. https://doi.org/10.1016/j.clay.2003.10.002
Veniale, F., Bettero, Jobstraibizer, A., Setti, M. 2007. Thermal muds: Perspectives of innovations. Applied Clay Science. 36, 141-147. https://doi.org/10.1016/j.clay.2006.04.013
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